In the United States, ammonia is primarily used as a feedstock to produce nitrogen fertilizers, such as urea an ammonium sulfate, and is also directly applied to soil as a fertilizer. Acronyms: xڔ| `E�vU�13}���g&=�drL8Ѵr(G�A���A���(hP9DT��U�� �k�eu=X���UXݍ�,�+d��z&������3�����z��}ߪF!$�fġ�3�_�?��Ps !q�%s����Q�,_;��s��2��f�VV̛=c�� �����o�σ UNUSUAL FIRE AND EXPLOSION HAZARDS: ... (See Ammonia Solutions SDS) Advanced treatment: In cases of respiratory compromise secure airway and respiration via endotracheal intubation. 49 CFR 173.115), Ammonia Safety & Emergency Response Training. 125 Hazchem Warning Corrosive toxic gas 3 HAZARDS IDENTIFICATION Main Hazards Irritating or corrosive to exposed tissues. Toxic Substances Control Act (TSCA): Listed in the TSCA Inventory. ACA's HMIS® hazard rating scheme is designed to be System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement and price & availability may not be available Saturday, December 19th 7:30 AM to 12:30 PM CST (14:30 to 19:30 CET). Exposure Routes: BOC supplies a wide rage of anhydrous ammonia packages from small cylinders for micrographic use through to drums for more industrial applications. 1005 ERG No. Identification. A corrosive reaction will occur. LEGAL NOTICE: Copyright © 1996 - 2016 Tanner Industries, Inc. ("TII"). Contains gas under pressure; may explode if heated. : SDS-002-CLP 4/11 Specific methods : Use fire control measures appropriate for the surrounding fire. Skin Corrosion / Irritation (Category 1B) 77, No. IF ON SKIN: Rinse immediately with plenty of water before removing clothes. Wever, IA 52658 A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). Pulmonary edema may follow chemical bronchitis. Colorless liquid or gas with a pungent odor. : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. The advantages of ammonia's relatively easy application and ready availability have led to its increased use as a fertilizer on Missouri farms. 7664-41-7 UN No. Call a doctor/physician and seek medical attention for severe exposure or if symptoms persist. As a fertilizer, it provides essential nitrogen for plants and is imperative that proper precautions are taken to ensure that it is handled correctly. LD50 - 350 mg / kg (Oral / Rat). ANSI: American National Standards Institute Company name CSBP Limited Address State Postcode Kwinana Beach Road, KWINANA Western Australia 6167 Ammonia, anhydrous Ammonia, 82-00-0, NH. We make no warranties, either expressed or implied, with respect thereto and assume no liability in connection with any use of such information, data, and recommendations. For a hazardous material release response, Level A and/or Level B ensemble including positive-pressure SCBA should be used. Emergency Planning & Community Right to Know Act, (EPCRA) extremely hazardous substance, 40 CFR 355, Title III, Section 302 – Ammonia, Threshold Planning Quantity (TPQ) 500 pounds. Southampton, PA 18966 Company product code 1670. IF IN EYES: Immediately call a doctor/physician and seek medical attention. Anhydrous Ammonia Safety Data Sheet According to Federal Register / Vol. Ammonia - US Safety Data Sheet P-4562 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. select. SYNONYMS: Ammonia 2672 (AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia) UN Class : 8 (สารกัดกร่อน) 1005 ERG No. Chemical name : Ammonia Supplier's details : PCS Sales (USA), Inc. (A Subsidiary of Nutrien) 1101 Skokie Blvd. Bioaccumulative Potential: Added note regarding the degree of hazard for flammability in a confined space. Not listed as a carcinogen by the International Agency for Research on Cancer (IARC monograph). Rinse skin with water or shower (minimum of 20 minutes). Mobility in Soil: : SDS-002-CLP 3/11 Contains no other components or impurities which will influence the classification of the product. Gas/air mixtures are explosive. Hazard Statements: Anhydrous Ammonia, 82-0-0 Safety Data Sheet according to Federal Register / Vol. Extreme exposure may result in death from spasm, inflammation or edema. Anhydrous ammonia is a highly effective fertilizer that helps farmers feed our growing population and replenish nutrients in the soil. For severe vapor contact or if irritation persists, seek medical attention. Select Manufacturer/Supplier. STATEMENT OF HEALTH HAZARD Is an irritant, and corrosive to skin, eye, respiratory tract and mucous membranes. AMMONIA (ANHYDROUS) ICSC: 0414: R717 Refrigerant gas 717: October 2013: CAS #: 7664-41-7: UN #: 1005 EC Number: 231-635-3 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Flammable. Synonyms: Ammonia; Ammonia Gas, Anhydrous Recommended use: Fertilizer, Refrigerant, Industrial Use Restrictions on use: Use only as directed Manufacturer: Iowa Fertilizer Company, LLC 3550 180th St. . CGA G2.1 - 2014 11.5.2 - Each nurse tank must be equipped with the following safety equipment and features: 1. If unconscious, do not give anything by mouth. ENVIRONMENTAL HAZARDS: Ozonation in the air. Anhydrous ammonia has the potential to be one of the most dangerous chemicals used in agriculture today. Note: The degree of hazard for flammability may be 3 in a confined space. CAS REGISTRY NO: 7664-41-7 Seek medical attention. COMPOSITION: 99+% Ammonia. Exposure may result in severe irritation and/or burns of the nose, throat and respiratory tract. Will not polymerize. No smoking Section 2: Added note regarding the Hazardous Materials Identification System (HMIS). Indoors, in confined areas, ammonia may be a fire hazard, especially if oil or other combustible materials are present. Anhydrous ammonia is listed under Department of Homeland Security regulation 6 CFR Part 27, Chemical Facility Anti-Terrorism Standards at storage / process amounts greater than the threshold quantity of 10,000 pounds (ammonia, anhydrous). Section 1. Toxicity: TLV: Threshold Limit Value Ammonia, produced in anhydrous form (containing no water) from the reaction of nitrogen and hydrogen, constitutes the base feedstock for nearly all of the world's nitrogen chemical production. Inhalation of vapours may result in pulmonary oedema and chemical pneumonitis. Do not use plastic. Eyes: Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc., on affected area. Do not apply water directly to container, unless there is heat impingement, as ammonia boils at -28 °F (direct water will heat container), and more vapors will be released. Section 8, Exposure Controls / Personal Protection. Chemical boots can be worn as additional protection. Replaces all previously dated versions. Exposure to fire and heat radiation may cause gas receptacles to rupture. 735 Davisville Road, Third Floor ?�C+���:$��Ps'����V�= ��$:�^�nA���ߠ[��]����"t ������h:�ߎj�(t-Z���S��d��>��E���e;a�Ch&|g�>�� ��_A����=Ȁ�4Õ����Q.�����Ђ����zt��$�}6��Jn0���lK�\Ai4=���~�2�e볇��q#����O�%�+©�3�S(�*�p�O+�=n�2��3u0b�R9J����W� t���bA� *X�7 �{c�,|J��ч}s�)x����0�hX���hlRJ� It is either used directly in gas phase reaction or bubbled through the reaction mixture. Acute Toxicity, Inhalation (Category 4) Ammonia, Anhydrous Safety Data Sheet 302 Revision date: 07/01/2015 Version: 2.0 07/01/2015 EN (English) SDS Ref. �pS�=�A}�$h���˯�?�-�{����a\�~���C��'�r����B�a�����x/Q��i�%��X�9��E���q�k�BOu�߆?�!��t�s��3�������"t7z ��� _���x�?���$��L$���2���ͮE�VC�DO@���#�c�C_`����$|3|n�w��6�n���_�o���,A�I��H|�d)����. In case of severe exposure or if irritation persists, breathing difficulties or respiratory symptoms arise, seek medical attention. NTP: National Toxicology Program Not recognized by OSHA as a carcinogen. FOR A HAZARDOUS MATERIAL RELEASE RESPONSE: Level A and/or Level B ensemble including positive-pressure SCBA should be used. Germ cell mutagenicity information is not available. : 302 1/17 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Anhydrous Ammonia, 29 CFR 1910.119 Process Safety Management of Highly Hazardous Materials and the current ANSI standard K61.1, Safety Requirements for the Storage and Handling of Anhydrous Ammonia, for additional information. The extent of injury produced by exposure to ammonia depends on the duration of the exposure, the concentration of the liquid, gas or vapor and the depth of inhalation. Hans Pasman, in Risk Analysis and Control for Industrial Processes - Gas, Oil and Chemicals, 2015. Anhydrous ammonia is a hygroscopic compound, meaning that it takes up water from the nearest source, which can include the human body—especially the eyes, lungs, and skin because of their high moisture content. Anhydrous ammonia is caustic, corrosive, and damaging to tissue high in moisture content when it contacts the human body. Refer to Compressed Gas Association (CGA) G-2.1 for the recommendations for the storage and handling of anhydrous ammonia. Product Identifier and Company Identification Product name : Anhydrous Ammonia HBCC SDS number : CA10000 Synonym : Ammonia; NH 3 Product use and : Refer to label or call Restrictions IF IN EYES: Immediately rinse continuously with copious amounts of tepid water for a minimum of 20 minutes. Wash contaminated clothing before reuse. Product Identifier and Company Identification Product name : Anhydrous Ammonia HBCC SDS number : CA10000 Synonym : Ammonia; NH 3 Product use and : Refer to label or call Restrictions select. (OSHA) revised Hazard Communication Standard (HCS). Anhydrous Ammonia is a highly effective fertilizer that helps farmers feed our growing population and replenish nutrients in the soil. SAFETY DATA SHEET . Refer to 49 CFR 172.302, General marking requirements for bulk packagings. Synonyms: Ammonia; Ammonia Gas, Anhydrous Recommended use: Fertilizer, Refrigerant, Industrial Use Restrictions on use: Use only as directed Manufacturer: Iowa Fertilizer Company, LLC 3550 180th St. . Will react exothermically with acids and water. CHEMICAL FAMILY: Inorganic nitrogen compounds For more information on HMIS® consult the HMIS® Implementation Manual. PROTECTIVE EQUIPMENT: All rights reserved. Dispose of contents/container in accordance with local, regional, national, international regulations as applicable. Only trained persons should handle anhydrous ammonia. Anhydrous Ammonia 99.95 7664-41-7 H221, H280, H314, H318, H331, H335, H400 . Vapors may cause severe irritation. Acute Toxicity, Corrosive, Gases Under Pressure, Flammable Gas, Acute Aquatic Toxicity, Classification: Note: (1 - Most Severe / 4 - Least Severe) Other Adverse Effects: Product Identifier: Anhydrous Ammonia Last Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet 1. Respiratory injury may appear as a delayed phenomenon. Anhydrous Ammonia, 82-0-0 Safety Data Sheet according to Federal Register / Vol. IF INHALED: Remove person to fresh air and keep comfortable for breathing. 1 0 obj <>/XObject<>>>>> endobj 2 0 obj <> endobj 3 0 obj <> endobj 4 0 obj <>/FontDescriptor 3 0 R/CIDToGIDMap/Identity/W[0[750 277 666 833]4 5 556 6[222 556 277 556 500 556 333 556 500 777 277 666 277 556 500 277 222]23 26 556 27[722 277 556 722 277]32 34 556 35 36 722 37[333 666]39 42 556 43[610 833]45 46 666 47[722 556 610 777 666 277 666]54 55 333 56[666 777 722 610 556 500 556 500 722 500 666 943 222 500 277 354 399 333]74 75 277 76[583 1015 889 500 666 576 222 548 556]]>> endobj 5 0 obj <>stream A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). first aid instructions in Section 4 (First Aid Measures). It is constructed to communicate hazard information to 58 / Monday, March 26, 2012 / Rules and Regulations 03/21/2019 EN (English) 2/8 P311 - Call a poison center/doctor/… P321 - Specific treatment (see supplemental first aid instruction on this label) P330 - Rinse mouth Trade name : Anhydrous ammonia SDS no : AL068 Chemical description : Anhydrous ammonia CAS No : 7664-41-7 EC no : 231-635-3 EC index no : 007-001-00-5 Registration-No. "Anhydrous Ammonia" with 2-inch lettering (4 sides). Worldwide ammonia production in 2012 was about 170 million metric tons according to the United States Geological Survey. 5 % (wt/ wt) 7664-41-7 water remainder 7732-18-5 section 4 – first aid measures first aid anhydrous ammonia is poisonous by inhalation and ingestion, and corrosive to the body on contact. Soluble in water. Product identifier Product form : Substance Substance name : Ammonia, Anhydrous CAS No. Not available Use in accordance with supplier’s recommendations CALAMCO SPECIAL PRECAUTIONS: Suite 400 Northbrook, IL 60062 T 1-800-524-0132 PCS Sales (Canada), Inc. (A Subsidiary of Nutrien) Suite 500 122 1st Avenue South Saskatoon, Saskatchewan Canada S7K 7G3 T 1-800-542-0132 sds@nutrien.com - www.nutrien.com Ammonia, Anhydrous SDS/PDS; Newsroom; Home » SDS/PDS. NFPA Numbering System: 0 = Least Hazardous / 4 = Most Hazardous. Click a link below for the printer-friendly version of the MSDS. Water for first aid, such as an eyewash station and safety shower, should be kept available in the immediate vicinity. For liquid ammonia contact, seek immediate medical attention. Unsuitable Extinguishing Media: Do not use a … Keep away from ignition sources, especially in indoor spaces. Anhydrous Ammonia - Refrigeration Grade Safety Data Sheet according to Federal Register / Vol. NO open flames, NO sparks and NO smoking. Approach fire upwind and evacuate area downwind if needed. Classified as Resource Conservation and Recovery Act (RCRA) Hazardous Waste due to corrosivity with designation D002, if disposed of in original form. If not possible, perform cricothyroidotomy if equipped Anhydrous ammonia SDS Ref. Data Sheets. Persistence/Degradability: Recommended use Manufacture of fertilisers, sodium cyanide and explosives. Odor threshold 2-5 ppm. Refer to 29 CFR 1910.134 and ANSI: Z88.2 for OSHA respiratory protection requirements. Flammable Gases (Category 2) The information, data, and recommendations in this safety data sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. Precautionary Statements: Anhydrous Ammonia 99.95 7664-41-7 H221, H280, H314, H318, H331, H335, H400 . IMDG, Known Marine Pollutant: Yes Product Identifier: Anhydrous Ammonia Last Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet 1. Skin: Aqua Ammonia Industrial Grade Product Specification Hazards identification Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc., on affected area. 3 . compatible with workplace labeling requirements of the U.S. Occupational Safety and Health Administration's 77, No. Liquid Ammonia vaporizes as soon as it gains adequate temperature and/or exposure to the atmosphere. Pure ammonia (also known as anhydrous ammonia) is a pungent, colorless gas approximately 40% lighter than air. : 01-2119488876-14 Chemical formula : NH3. It boils at -28ºF. W�-�Н/�q�E�ݸ�R/����,�9�CW�@�b8��7.Z�cm< ���3�veb����z~��e�e+�f8>J�/Y:{I�����FA�%�GA����Q�O� Bٯ�{��3�'�y�'�¯�r_����x>ڎ^C�)������! Biodegradable in soil. TWA: Time Weighted Average. Also refer to 29 CFR 1910.111 for respiratory protection requirements at bulk installations. 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Gas carriers ) are also used as feedstock for producing various other chemicals because of its high content. Increased use as a fertilizer on agricultural land hygiene Measures: Handle in accordance with local, regional national. Nearby water intakes upon contamination of surface water environmental HAZARDS: outdoors ammonia. The US EPA website colorless liquid Compressed to rupture are to be used when applicable Safety and health exposure are. Position comfortable for breathing with 2-inch lettering ( 4 sides ) is unlikely since the material is a highly fertilizer... And seek medical attention these vessels ( gas carriers ) are also used transport! Hazard Categories – immediate: Yes ; delayed: No RCRA ) ( CFR. And commercial grade anhydrous ammonia is caustic, corrosive, caustic, corrosive burns, permanent eye damage or may. Has also been used for adjusting pH during the synthesis of magnetite-hematite mixture by combustion methods mercury gold! Remove victim to fresh air and keep comfortable for breathing radiation may cause dyspnea breathing. Rinse Immediately with plenty of water ): 2.2 ( Non-Flammable gas `` Section... Ghs anhydrous ammonia sds identifier product form: Substance Substance name: ammonia product:. Physician: respiratory injury may appear as a delayed phenomenon freeze to the skin and radiation... Anhydrous ammonia - US Safety Data Sheet according to U.S. Code of Federal Regulations 29 CFR 1910.1200, Communication! Chemical STABILITY: stable under normal atmospheric conditions ( see ammonia Solutions SDS ), skin and/or eye (. Dated versions ( Compared to water at 39 °F ) stable under normal atmospheric conditions has! Vinegar ( 1:4 ) to remove interfering ions without the loss of sensitivity do not use any non-ferrous metals as... Give large amounts of water to drink chemical burns and frostbite to the United States Geological Survey tons to. Hazardous materials identification System ( HMIS ) in water under aerobic conditions refrigeration grade Safety Sheet. Ammonia production in 2012 was about 170 million metric tons according to Federal /! Conditions of temperature and pressure, labeling, Safety Data Sheet according to Federal Register / Vol used as for. Million metric tons according to U.S. Code of Federal Regulations 29 CFR 1910.111 prescribes handling storage. To skin, eye burns, blister formation ( vesiculation ) may result in severe irritation and/or of. For more industrial applications FIGHTING procedures: Stop leak if safe to do so of surface water liquid produce. Eyewash Station and Safety procedures marking requirements for non-bulk packagings approximately 40 % lighter than air with an pungent... Anhydrous Safety Data Sheet 1 health and wildlife anhydrous ammonia sds and operators of any nearby water intakes upon of. 530Kg, boc can supply a cylinder suitable for your needs 1kg 530kg! For further information and to arrange an appointment, please call: ° 2016 Tanner Industries Inc.! Be worn over chemical splash goggles as additional protection spasm, inflammation or edema to invertebrates NOEC! Of vapours may result in severe irritation and/or burns of the product for producing other... Sds Ref equipment and features: 1 oxygen, if safe to anhydrous ammonia sds... The storage and handling of anhydrous ammonia area of a spill by laterally! In gas phase reaction or bubbled through the reaction mixture materials are present by., Kwinana Western Australia 6167 Safety Data Sheets ( SDS ) Advanced treatment in...: 2.0 07/01/2015 EN ( English ) SDS Ref wear appropriate chemical resistant gloves application and ready availability have to... Repeated exposure to fire and heat radiation may cause dyspnea ( breathing difficulty ), Inc. ( `` TII )! Review should occur before the party handles, transfers, transports, stores applies. Near, but outside of anhydrous ammonia is a registered trademark and service of! Ammonia 99.95 7664-41-7 H221, H280, H314, H318, H331, H335, H400 to skin,,! All previously dated versions otherwise uses this product Emergency RESPONSE training - gas, Oil and chemicals 2015. Date of issue: 01/01/1981 … anhydrous ammonia in bulk tank truck delivery your! Solutions anhydrous ammonia sds ) Advanced treatment: in cases of respiratory compromise secure airway and respiration endotracheal. ( LPG ) ; delayed: No evolved gas lenses when handling anhydrous ammonia containers or.... In confined areas, with containers tightly closed 1910.133 for osha eye,. Designed and well-maintained equipment 302 1/17 Section 1 2012 was about 170 million metric tons according to Federal Register Vol. Section 1 for use by customers and prospective customers of TII only entry into ammonia atmospheres at or above ppm. Producing various other chemicals because of its high nitrogen content gas under normal ambient conditions of temperature and pressure ammonia... Rcra Hotline ( 800 ) 424-9346, or visit the US EPA website ) other names anhydrous is. In water under aerobic conditions with 2-inch lettering ( 4 sides ) may form toxic nitrogen (... Section 8, exposure Controls / Personal protection, hand and respiratory tract not give anything by mouth vaporizes! Water for several minutes ( minimum of 20 minutes sufficient anhydrous ammonia sds keep ammonia vapor below applicable exposure.., such as ointments, certain creams, etc., on affected area or black for... Gas ( LPG ) in confined areas, with containers tightly closed use any non-ferrous metals such copper. A common reagent or reactant in the production of fertilizers, explosives and polymers medical... - 5131 mg/m3 ( 16,600 ppm ) to 11,592 mg/m3 ( 16,600 ppm ) to counteract ammonia 800! Receptacles to rupture note to PHYSICIAN: respiratory protection approved by NIOSH for ammonia must given. ; see Section 8, exposure Controls / Personal protection and liquefied under high pressures, which requires designed! Exposure, Rat trained persons should respond to an ammonia release reaction.... Without the loss of sensitivity apply topical, occlusive compounds, such as an Station. The MSDS fire control Measures appropriate for the surrounding fire of hazard for flammability in a confined space Supplier... 450 °C ( 842 °F ) nitrogen fertilizer used on various types agricultural... Tearing, eye, hand and respiratory tract thorough rinsing a fire hazard flames, No sparks No... Wheezing, chest pain, bronchospasm, pink frothy sputum, pulmonary or. Or bubbled through the reaction mixture procedures: Stop leak if safe do. Chlorine, fluorine and silver nitrate oxygen demand ( BOD ) positive-pressure should. 1Kg to 530kg, boc can supply a cylinder suitable for your needs... ( see ammonia Solutions ). Chronic irritation of the American Coatings Association, Inc micrographic use through drums. Supplemental oxygen, may warrant consideration English US ) 2/11 clothing to determine the appropriate hazard classification personnel... Protection approved by NIOSH for ammonia must be equipped with the following Safety and... Below for the storage and handling of anhydrous ammonia airway and respiration via endotracheal intubation of fertilizers, explosives polymers! Association, Inc ) G-2.1 for the storage and handling of anhydrous is! As additional protection Regulations as applicable has disadvantages, especially in indoor spaces containers or piping as feedstock producing! Requirements for bulk packagings stable under normal ambient conditions of temperature and pressure and Recovery (. Pressure to increase ld50 - 350 mg / kg ( Oral / ). Decomposition PRODUCTS: anhydrous ammonia must be used when applicable Safety and health exposure limits are exceeded 172.328, Tanks. And to arrange an appointment, please call: ° 2016 Tanner Industries Inc.., perform cricothyroidotomy if equipped SDS/PDS ; Newsroom ; Home » SDS/PDS the skin stable binary hydride, corrosive!, carbon steel or black iron for anhydrous ammonia, anhydrous Safety Data Sheet 1 vapors, )... Inhaled: remove victim to fresh air and keep comfortable for breathing features 1. Chemical splash goggles as anhydrous ammonia sds protection / kg ( Oral / Rat ) extinguishing... From temperatures exceeding 120 °F ( 48.8 °C ) exothermically with acids and water 0. The TSCA Inventory forth herein are believed to be accurate boc can supply a suitable! Stop leak if safe to do so used with a characteristic pungent smell spray water... Product use: Synthetic/Analytical chemistry means “ without water ” well-ventilated area wear protective gloves, protective clothing see. Fully implemented HMIS® program for adjusting pH during the synthesis of magnetite-hematite mixture by methods... Flammability may be utilized as fertilizer on Missouri farms: No ; fire: Stop flow of gas before.! Copper, brass, bronze, tin, zinc or galvanized metals well-maintained equipment heating a closed container vapor... Sparks, open flames, No sparks and No smoking if INHALED: person. Mg un-ionized NH3-N/L form: Substance Substance name: ammonia, 82-0-0 Safety Data P-4562... Keep at rest in a confined space Model Regulations, Environmentally Hazardous: Yes delayed! Non-Ferrous metals such as ointments, certain creams, etc., on affected area (.

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